Heptane Totally Explained

Everything about Heptane totally explained

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n-Heptane is the straight-chain alkane with the chemical formula H₃C(CH₂)₅CH₃ or C₇H₁₆. It is the zero point of the octane rating scale.

Uses

Heptane (and its many isomers) is widely applied in laboratories as a totally non-polar solvent. A liquid, it's ideal for transport and storage. In the grease spot test, heptane is used to dissolve the oil spot to show the previous presence of organic compounds on a stained paper. This is done by shaking the stained paper in a heptane solution for about half a minute. Extraction into heptane is a means by which aqueous bromine may be distingiushed from aqueous iodine. In water, both bromine and iodine appear brown. However, iodine turns purple when dissolved in heptane, whereas the bromine solution remains brown.
Heptane is commercially available as the rubber cement solvent Bestine.

Octane rating scale

n-Heptane is the zero point of the octane rating scale. It is undesirable in petrol, because it burns explosively, causing engine knocking, as opposed to branched-chain octane isomers, which burn more slowly and give better performance. It was chosen as the zero point of the scale because of the availability of very high purity n-heptane, unmixed with other isomers of heptane or other alkanes, distilled from the resin of Jeffrey Pine and from the fruit of Pittosporum resiniferum. Other sources of heptane and octane, produced from crude oil, contain a mixture of different isomers with greatly differing ratings and don't give as precise a zero point.

Isomers and enantiomers

Heptane has nine isomers, or eleven if enantiomers are counted:

Heptane (n-heptane), H₃C–CH₂–CH₂–CH₂–CH₂–CH₂–CH₃, straight chain of seven carbon atoms.
2-Methylhexane, H₃C–CH(CH₃)–CH₂–CH₂–CH₂–CH₃, chain of six carbon atoms, and a methyl group attached to the second.
3-Methylhexane, H₃C–CH₂–C^*H(CH₃)–CH₂–CH₂–CH₃ (chiral), chain of six carbon atoms, and a methyl group attached to the third.
2,2-Dimethylpentane, (H₃C)₃–C–CH₂–CH₂–CH₃, chain of five carbon atoms, and two methyl groups attached to the second.
2,3-Dimethylpentane, (H₃C)₂–CH–C^*H(CH₃)–CH₂–CH₃ (chiral), chain of five carbon atoms, and methyl groups attached to the second and third.
2,4-Dimethylpentane, (H₃C)₂–CH–CH₂–CH–(CH₃)₂, chain of five carbon atoms, and methyl groups attached to the second and fourth.
3,3-Dimethylpentane, H₃C–CH₂C(CH₃)₂–CH₂–CH₃, chain of five carbon atoms, and two methyl groups attached to the third.
3-Ethylpentane, H₃C–CH₂–CH(CH₂CH₃)–CH₂–CH₃, chain of five carbons, and an ethyl group attached to the third.
2,2,3-Trimethylbutane, (H₃C)₃–CH(CH₃)–CH₃, chain of four carbon atoms, with two methyl groups attached to the second, and one to the third.(External Link)

Further Information

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